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Volume 1, Issue 1, 2024
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Advanced Gyrotron Concepts for Spectroscopic Applications
Authors: Vladimir Evgen'evich Zapevalov and Andrey Sergeevich ZuevBackgroundCurrently, some modern spectroscopic applications require sub-terahertz and terahertz continuous-wave electromagnetic radiation sources with power levels from 0.1 to 100 W. Gyrotron, a powerful high-frequency vacuum electronics device, is considered one of the promising sources for these aims.
MethodsModification of the gyrotron design promotes the widespread use of these devices for DNP/NMR spectroscopy.
ResultsPromising non-canonical concepts are presented, the features of which compare favorably with the classical gyrotron scheme.
ConclusionThe gyrotron concepts we considered allow us to master the terahertz range and develop a unique gyrotron installation for each scientific group, considering the specifics of their scientific research.
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The Mass Gap in QCD and a Restriction on Gluon Masses
More LessIn this study, we prove that it is necessary to introduce the non-zero gluon masses into the fundamental Lagrangian of Quantum Chromodynamics in order to describe the mass gap in the reaction of electron-positron annihilation into hadrons. Further, in this work, a new restriction on the gluon masses is imposed, and the renormalized theory with non-zero Lagrangian gluon masses is presented.
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Understanding the Origins of Quark Charges, Quantum of Magnetic Flux, Planck’s Radiation Constant and Celestial Magnetic Moments with the 4G Model of Nuclear Charge
More LessIntroductionIn our previous published papers, considering 3 large atomic gravitational constants assumed to be associated with weak, strong and electromagnetic interactions, we have proposed the existence of a nuclear charge of magnitude, en=2.95e and developed a nuclear mass formula associated with strong and weak interactions having 4 simple terms and only one energy coefficient.
MethodsTwo important assumptions are that there exists a weak fermion of rest energy 585 GeV and strong coupling constant is the squared ratio of electromagnetic charge and nuclear charge. The aim of this paper is associated with understanding the mystery of the quantum of magnetic flux, Planck’s quantum radiation constant and Reduced Planck’s constant. Proceeding further, quark charges, strong coupling constant, nuclear stability, nuclear binding energy, medium and heavy atomic X-ray levels and celestial magnetic moments can be understood in a unified approach. It may also be noted that, by considering the integral nature of elementary particle masses, it seems possible to understand the discreteness of angular momentum.
ResultsConsidering our proposed en=2.95e=3e as a characteristic nuclear charge, it seems possible to understand the integral nature of quarks electromagnetic charge. With this idea, neutron, proton and pion decay can be understood very easily.
ConclusionIn all the cases, the up quark of charge (±2e) seems to play a crucial role in the internal transformation of the down quark of charge (±e) and external observable elementary basic elementary particles. It needs further study at the fundamental level. Proceeding further, quantum of magnetic flux, Planck’s radiation constant and Reduced Planck’s constant can be understood with our 4G model of final unification.
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Variations in the Solar Modulation Parameter Over the Last 9.5 Thousand Years and the Tilt of the Geomagnetic Dipole
Authors: Sergey S. Vasiliev and Valentin A. DergachevBackgroundCalculations of the solar modulation parameter (Φ) over the past millennia typically use the relationship between the production rate of cosmogenic isotopes, the earth's dipole moment, and the magnitude of Φ. The cosmogenic isotopes 14C and 10Be are typically used in these studies. When studying solar modulation, the cyclic change in dipole tilt is usually not taken into account, which affects estimates of past solar activity.
MethodsTree rings are a reliable basis for obtaining a radiocarbon time scale (IntCal13). However, determining the concentration of 14C in tree rings is a difficult and controversial task. The time scale derived from the 10Be production rate simulation (GICC05) is less reliable. Nevertheless, there is a way to combine the accuracy of the radiocarbon time scale with the reliability of estimates of the 10Be production rate. This method is the synchronization of the radiocarbon and beryllium-10 series.
We have selected the most relevant methods for calculating the solar modulation parameter Φ for the Holocene. When calculating Φ, 10Be data synchronized with 14C data were used. The latest data on the earth's dipole moment were considered. Empirical Mode Decomposition (EMD) was used in the analysis of Φ.
ResultsIt has been shown that the first two decomposition modes are oscillating components with periods of 710 and 208 years, the amplitudes of which increase with time, reaching a maximum of 2500 BP. From contemplation, it follows that the 710-year oscillations are apparently caused by fluctuations in the tilt of the earth's dipole. After excluding the EMD component associated with the 710-year cyclicity, a corrected series was obtained for the solar modulation parameter, free from the influence of changes in the tilt of the magnetic dipole.
ConclusionThe rate of formation of cosmogenic radionuclides depends on the intensity of penetration of Galactic Cosmic Rays (GCRs) into the earth's atmosphere. Before reaching earth, GCRs must cross the heliosphere, where they are exposed to solar modulation. Adequate consideration of solar modulation parameters is important for the correct interpretation of the rate of production of cosmogenic isotopes and solar activity.
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Measurement of Viscoelastic Properties by Free Loading-Mass Method
By Kulik V.M.BackgroundA procedure for determining the elastic and viscous properties of the sample material on the basis of the forced vibrations of a sample of mass 𝑚 loaded with a certain mass 𝑀 is developed. One of advantages of using the top mass instead of a rigid fixation is the appearance of an additional deformation resonance, the frequency of which is times smaller than the resonance frequency of the fixed sample.
MethodThe experimental setup implementing the free mass method is described. Notably, the proposed scheme does not require any adjustment and is assembled from standard devices. By changing the design of the sample only, both shear and compression-tension strains can be measured. The combination of these methods allows measuring the complex Poisson’s ratio, in addition to modulus of elasticity and loss factor.
ResultsOne-dimensional (1D) and two-dimensional (2D) models of specimen deformation are considered. For the 1D deformation model, approximate formulas for calculating the modulus of elasticity and the loss factor are substantiated and the limits of validity these formulas are outlined. Improving the accuracy of measurements is also considered. To do this, it is necessary to fully describe the boundary conditions on the deformable sample. The developed 2D model of sample deformation made it possible to calculate the elastic modulus form factors for various samples with axial symmetry.
ConclusionThe method may become a Standard for measuring viscoelastic properties of materials (complex elastic and shear modulus, as well as complex Poisson's ratio).
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Advancements of Lanthanide-doped Phosphors in Solid-state Lighting Applications
More LessThe challenge of energy conversion and enhancement has been a problem in the world of lighting technologies as the population and global industrialization grow rapidly. Solid-state lighting (SSL) has proven to be a better alternative in the illumination industry because of its environmentally friendly and high energy efficiency. Lanthanide-doped phosphors have gained global attention in SSL because they have versatile applications with enhanced overall performance and luminescence. This review delves into the advancement in lanthanide-doped phosphors for Solid-state lighting (SSL) applications. It discusses the in-depth analysis of how to tailor the crystal lattice design, optimize the host material for emission efficiency, and minimize the non-radiative pathways. This paper further discusses the lanthanide-doped phosphor composition, strategies to obtain desired emission spectra, and enhanced color rendering index with the Energy transfer mechanism and the synthesis techniques. This review also addresses 3 processes for expanding the light spectrum, current challenges, future directions, and emerging trends present in the lanthanide-doped phosphor in Solid-state lighting (SSL) applications.
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NiO@PANI based Nanocomposites as an Advanced Functional Material: Experimental and Computational Approach
Authors: Harish Kumar and Manisha LuthraBackgroundIndividually, metal nanoparticles (NPs) and conducting polymers show unique properties due to small size, large surface area, and high order of conductivity. But their combination may result in a synergistic effect in properties.
MethodsThe NiO NPs and conducting polymer Polyaniline were prepared by modified Sol-gel and chemical oxidative methods, respectively. Powder XRD, FTIR, TEM, and UV-visible methods were used for the structural evaluation. The computational (DFT) study was performed to support experimental results. The NiO/Polyaniline (PANI) nanocomposites (NCs) were explored as corrosion inhibitors, electrical conductors, and photocatalytic agents.
ResultsThe NiO/Polyaniline NCs showed 91.52% corrosion inhibition efficiency at 1000 ppm concentration. The photocatalytic activity was investigated against methylene blue dye under ultraviolet light. The NiO/Polyaniline NCs decompose 90% of organic dye. The NCs exhibit good conducting, corrosion inhibition, and photocatalytic activity.
ConclusionThe metal oxide (NiO NPs) and PANI-based NCs can be used as corrosion inhibitors, conducting material, and for the degradation of organic compounds (dyes) in impure water.
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Sputtering Heterogeneous Tungsten Carbide Targets by Light Ions Bombardment
More LessBackgroundThis paper presents a model for sputtering heterogeneous two-component materials with light ions.
MethodsThe model, based on two sputtering mechanisms, makes it possible to calculate the total sputtering coefficients of the target components, and it is easily transformed for the case of sputtering different types of targets. Model testing was conducted for the case of sputtering homogeneous tungsten carbide targets with ions of different energies.
ResultsThe results of the calculations are given in comparison with experimental data and the results of computer simulation. The comparison shows good agreement of the calculated values with the data of other authors. The proposed model was used to describe stationary (stoichiometric) sputtering of tungsten carbide targets. Using this model, the concentrations of components in the modified target layer were calculated, and the thickness of the modified layer was also estimated.
ConclusionThe method of calculating the concentration of target components in the modified layer and the thickness of this layer can be the basis of the technology of creating materials with given properties of the surface layer.
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High-power Microwaves Against Locust Invasion
More LessBackgroundThere are a lot of phytophagous and harmful animals in agriculture and forestry in the entire world. The ultimate goal in locust control is the use of preventive and proactive methods that disrupt the environment to the least possible extent. This would make agricultural production easier and more secure in the many regions where growing crops is of vital importance.
MethodsThe possibility of using high-power microwave systems to combat harmful animal pests in agriculture and forestry is discussed. The proposed method is compared favorably with respect to the environment.
ResultsThe obtained results of the study demonstrated the possibility of using modern sources of high-power microwave radiation to solve the problem of insect invasion.
ConclusionIt should be noted that the use of powerful microwaves is a promising means of controlling locusts and other pests. Mobile international forces equipped with modern microwave apparatus can solve the problem of combating locusts and other pests on a global scale without harming the environment. Microwave systems can also be used against other phytophagous pests of agriculture and forestry.
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Tailoring Ti3C2Tx MXene Flake Sizes for Modified Electrochemical Performance: A Top-down Approach
Authors: Yuchao Fan, Xu Mei, Li Ye, Qingyong Tian, Renqi Zhang, Yingjiu Zhang and Xinjian LiIntroductionTwo-dimensional (2D) materials, such as MXene (Ti3C2Tx), have garnered extensive attention in recent years due to their exceptional performance across various domains. The flake size of Ti3C2Tx notably influences its specific surface area, a pivotal factor in interfacial interactions within electrochemistry.
MethodsPresently, modifying the flake size of bulk Ti3C2Tx typically involves complex and costly processes, like ultrasonic treatment and isolation. Leveraging the specific preparation principle of MXenes, which involves etching the A layers in precursor MAX phases, a top-down strategy for producing Ti3C2Tx flakes of desired sizes, has been proposed in this work. In this approach, precursor Ti3AlC2 particles undergo ball-milling to adjust their size.
ResultsThrough this innovative strategy, dispersions of Ti3C2Tx flakes with varying average lateral sizes are generated, enabling an investigation into the impact of lateral size on the electrochemical properties of Ti3C2Tx flakes. By controlling the ball milling time for Ti3AlC2 powders, the resulting average sizes of Ti3C2Tx (0, 2, 4) are 6.34 μm, 2.16 μm, and 0.96 μm, respectively. Particularly, the Ti3C2Tx (2) electrode, composed of 2.16 μm sheets, demonstrates remarkable performance metrics. It exhibits a high areal capacitance of 845.0 mF/cm2 at a scan rate of 5 mV/s, along with a gravimetric capacitance of 244.0 F/g at a current density of 1 A/g.
ConclusionThis study presents a facile method to enable mass production of Ti3C2Tx with sheets of varying sizes, addressing both small and large dimensions.
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Laboratory Analogs of Thermally Processed Ices Containing H2O, N2, NH3, CO2, and C2H3N Relevant to Astrophysical Environments
More LessIntroductionLaboratory simulations can benefit ground- and space-based observations of icy bodies in outer space. It is well-known that NH3 and CO2 can interact, forming ammonium carbamate (CH6N2O2).
MethodsThis study examines NH3 and CO2 in thermally processed H2O-rich ices in the laboratory via mid-infrared absorption spectroscopy. In particular, the presence of CO2 in NH3-ice mixtures thermally annealed at 150 K for more than four hours in systematic experiments suggested that ammonium carbamate could potentially trap volatiles within the ice matrix.
ResultsAdditional studies with acetonitrile (C2H3N) in ice mixtures containing H2O, CO2, and NH3 were also performed. Absorption peak position changes were recorded when the temperature was slowly increased (≤ 5K/min) and also annealed at temperatures up to 150 K.
ConclusionThese studies will hopefully be useful in interpreting pre-biotic chemistry in the Solar System.
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Synthesis of Optimal Control of Spacecraft Angular Momentum for Spatial Turn Taking into Account Energy Costs Using Quaternions
More LessBackgroundIn this paper, we propose solving the specific original problem of control synthesis of spacecraft attitude. Optimization of the control program is made with the use of a new criterion of quality that combines energy costs and duration of reorientation under restrictions on control (the presence of a time factor limits the duration of slew maneuver).
MethodsThe construction of optimal control for angular momentum change is based on the quaternion method and L.S. Pontryagin maximum principle. An analytical solution to the problem was obtained on the base of a differential equation relating the orientation quaternion and angular momentum of a spacecraft.
ResultsKey properties of the optimal solution are formulated in analytical form; the features of optimal motion are studied in detail. The control law is formulated in the form of explicit dependence between control and phase variables. In a case when the controlling torque is limited by the given restriction (at the beginning and end of a turn), analytical formulas have been written for the duration of braking and acceleration. Main relations which determine optimal values of parameters of the algorithm for control of angular momentum are given. Examples and results of mathematical modeling of spacecraft motion formed by optimal control were given. This data in addition to the theoretical descriptions illustrates the process of reorientation in evident form and demonstrates the practical feasibility of a designed method for control of angular momentum during spatial turn.
ConclusionThe designed optimal algorithm of control of spacecraft motion improves the efficiency of spacecraft attitude system, and originates more economical performance of spacecraft during flight on orbit.
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