Current Green Chemistry - Online First
Description text for Online First listing goes here...
-
-
Expression of Concern: Recent Advances in Green Catalysis and Drug Discovery- Part 1
Available online: 16 December 2025More Less
-
-
-
Expression of Concern: Recent Advances in Green Catalysis and Drug Discovery: (Part 2)
Available online: 16 December 2025More Less
-
-
-
Insight on Assessment of Toxins and Heavy Metals in Food Products - A Concise View on Analytical Approach and Methods
Authors: Pawan Kumar Goswami, Ranjeet Kumar and Dharmendra KumarAvailable online: 15 October 2025More LessIntroductionWith the globalization of food supply chains, food safety has emerged as a critical global concern impacting public health, well-being, and economic stability. Chemical contaminants such as mycotoxins and heavy metals pose significant health risks, necessitating advanced detection and monitoring strategies to ensure food safety.
MethodsA literature search was conducted in PubMed, Scopus, Web of Science, and ScienceDirect (2010-2025) using keywords like “food safety”, “heavy metals detection”, and “sample preparation…” Relevant studies were screened and reviewed to evaluate recent advancements in analytical technologies and sample preparation methods. Techniques such as SERS, ICP-MS, AFS, and AAS were assessed for sensitivity and accuracy, while novel preparation methods (microwave-assisted digestion, ultrasonic extraction, slurry, and direct solid sampling) were analyzed for efficiency. Speciation analysis of arsenic and mercury was also included to address bioavailability and toxicity.
ResultsAdvanced analytical methods showed superior sensitivity and rapid detection of trace contaminants. Microwave-assisted digestion and ultrasonic extraction enhanced sample preparation by reducing analyte loss and improving recovery rates. Direct solid sampling (e.g., graphite furnace AAS) and speciation analysis proved critical for assessing toxicological relevance.
DiscussionThese findings highlight the potential of integrating cutting-edge analytical technologies and improved sample preparation methods into routine food analysis. They address challenges of trace-level detection and offer strategies for mitigating chemical hazards in the food chain.
ConclusionAdopting advanced analytical and sample preparation techniques, supported by strengthened regulatory frameworks, is essential to ensuring food quality and safety and protecting public health globally.
-
-
-
Biodegradable Food Materials for the Removal of Dyes from Aqueous Solution: Sustainable and Circular Approach for Food Waste Management
Available online: 05 August 2025More LessDye pollution is unsightly and harmful to the environment because it lowers oxygen levels in water and inhibits photosynthesis. The need for biodegradable polymers that can efficiently absorb pollutants is driven by the frequent failure of conventional treatment procedures to effectively remove dyes. The present study aimed to explore the applications of biodegradable natural components, including starch, cellulose, chitosan, and food waste derivatives, in removing dyes from wastewater. The review analysed relevant literature on biodegradable food materials for the removal of dyes from aqueous solution. The review articles were obtained through databases, including ScienceDirect, Scopus, PubMed, and Google Scholar. This review gathered relevant data, preferably from the last 10 years, on bioadsorbents for dye removal and waste management. Biodegradable adsorbents have shown great promise for dye removal due to their eco-friendliness, but their effectiveness depends on several factors. These include surface area, pH, and material modifications that enhance adsorption properties. Electrostatic interactions, ion exchange, hydrogen bonding, and π-π interactions play key roles in the dye adsorption process. Although these materials can be reused after dye removal, maintaining their efficacy over multiple cycles often requires chemical or thermal regeneration. Cost-effective scaling and the development of green regeneration techniques are still needed for practical applications. Dye removal is possible using biodegradable materials. Although these materials are effective with certain modifications, further research is needed to develop cost-effective scaling methods and environmentally friendly regeneration processes.
-
-
-
Microwave-assisted Synthesis and Characterization of Calix[4]resorcinarene Schiff Base [C4RSB]
Authors: Parin H. Kanaiya, Vinod K. Jain and Mayank G. SharmaAvailable online: 05 August 2025More LessBackground/IntroductionCalix[4]resorcinarenes are macrocyclic hosts with wide-ranging applications in catalysis, molecular recognition, and materials science. Functionalization through Schiff base formation can enhance their stability, selectivity, and binding properties. Traditional synthetic approaches are often time-consuming, energy-intensive, and environmentally unfriendly.To develop a rapid, energy-efficient, and eco-friendly microwave-assisted protocol for synthesizing structurally diverse calix[4]resorcinarene Schiff base (C4RSB) derivatives in high yields, while adhering to green chemistry principles.
MethodA series of C4RSB derivatives was synthesized under mild conditions using ethanol as a green solvent and microwave-assisted heating. The reaction parameters were optimized to maximize yield and minimize energy consumption. The resulting compounds were characterized by NMR, FTIR, elemental analysis, and mass spectrometry to confirm structural fidelity, purity, and reproducibility.
ResultsThe microwave-assisted methodology yielded C4RSB derivatives in excellent yields (80–91%) with significant reductions in reaction time and energy usage compared to conventional methods. Spectroscopic analyses confirmed the successful formation of imine linkages and the preservation of the calix[4]resorcinarene framework. The methodology proved robust and reproducible, generating structurally consistent products.
DiscussionMicrowave-assisted synthesis of C4RSB derivatives achieved high yields with markedly reduced reaction times, underscoring its efficiency over conventional methods. The use of ethanol as a green solvent minimized environmental impact while maintaining product purity and structural integrity, as confirmed by spectroscopic analysis. Enhanced reaction kinetics under microwave irradiation facilitated rapid imine formation without thermal degradation, demonstrating the method’s suitability for sustainable, scalable macrocycle functionalization.
ConclusionMicrowave-assisted synthesis using ethanol as a green solvent provides an efficient, sustainable, and high-yielding route to C4RSB derivatives. This approach aligns with green chemistry principles and holds promise for the scalable production of functionalized calix[4]resorcinarenes for catalysis, molecular recognition, and advanced materials development.
-
-
-
Production and Multidisciplinary Applications of Bioplastic: A Biodegradable and Eco-Friendly Alternative to Plastic
Authors: Ajesh Chauhan, Shivam Rajput, Rishabha Malviya and Sathvik Belagodu SridharAvailable online: 05 August 2025More LessThe versatility of plastics has led to their widespread use. The use of plastic has increased twentyfold in the previous half-century, and scientists anticipate that it will increase further in the subsequent two decades. Roughly 330 million metric tons of plastic is produced annually on a worldwide scale. A relatively recent and persistent issue in environmental management is the production, usage, and eventual disposal of plastics. Millions of animals perish annually, and soil fertility is diminished as a result of plastics building up in the ecosystem due to improper disposal. One solution to the environmental problems caused by polymers made from petrochemicals is the development of bioplastics, which are biodegradable and functionally equivalent to conventional plastics. Bioplastics and their derivatives have the potential to revolutionise environmental sustainability by reducing emissions of greenhouse gases and facilitating their widespread application. To find a long-term solution to the problem of plastic pollution, bioplastics must be developed further. It is crucial to raise public awareness to tackle plastic pollution in a sustainable manner. Concerns about pollution and the depletion of fossil fuel resources have prompted a dramatic increase in the study and creation of sustainable alternatives. Bioplastics made from sustainable plants provide a practical answer to these problems. This review article examined existing studies on the production, use, and multidisciplinary applications of bioplastics as biodegradable and environmentally friendly alternatives to conventional plastics. Research articles were collected from databases such as ScienceDirect, Scopus, PubMed, and Google Scholar. The review focused on highlighting the growing significance of bioplastics by analysing their production methods, diverse applications, and potential benefits across various sectors. This review will examine the many plant-based bioplastics, their production process, and their various uses in different sectors. Along with the opportunities and threats associated with bioplastics' potential future commercialisation, this paper explains the positive side along with the limitations of these environmentally friendly materials.
-
-
-
Sustainable Tools for C-C and C-heteroatom Cross-coupling from Aryl Diazonium Salts
Authors: Atanu Mahata and Debasish KunduAvailable online: 22 July 2025More LessAromatic and heteroatomic diazonium salts constitute a significant class of very reactive electrophiles. In recent times, reactions of diazonium compounds under visible-light photocatalysis, microwave irradiation, and ball-milling strategies have been at the forefront of organic synthesis. The anions like tetrafluoroborate, mesylate, tosylate, disulfonamide, except for chloride and carboxylate, tethered with the aromatic rings of diazo frameworks, have rendered exceptional stability. The synthetic methodologies are highly advantageous in terms of regioselectivity of yields, broad substrate scope, excellent functional group tolerance, and high conversion ratio. These sustainable approaches not only reduce waste production, but also facilitate a ubiquitous eco-friendly protocol which enables strategies, transformations, and syntheses that are typically unachievable in solution. This current review article summarizes the recent developments of aryl diazonium compounds in the field of organic synthesis under ligand- and additive-less conditions. The sustainable techniques employed herein involve the use of non-toxic, low-cost, commercial-grade reagents, environmentally benign and greener solvents.
-
-
-
Advanced Strategies for Enhancing Analytical Techniques of Solid Phase Microextraction: An Overview
Authors: Shivam Kumar, Ranjeet Kumar and Dharmendra KumarAvailable online: 18 July 2025More LessSolid-phase microextraction (SPME) is a popular technique for sample preparation, known for reducing the need for solvents and integrating well with chromatography instruments. Recent advancements focus on improving extraction efficiency through new coating materials. Despite improvements in analytical instruments, sample preparation remains a challenge, especially for detecting trace substances. This review explores the latest developments in SPME, particularly new coating materials, including nanomaterials like metal oxide nanoparticles, metal nanoparticles, carbon-based nanomaterials, and silica nanoparticles. These materials improve enrichment, analyte selectivity, and resistance to interference. The review also examines how analyte properties and coating composition affect extraction performance, helping researchers design better coatings. Additionally, the manuscript discusses modern applications of SPME, such as direct coupling with mass spectrometry and in vivo sampling, highlighting its growing importance in analytical fields. By summarizing recent innovations and applications, this review aims to provide valuable insights into developing more effective SPME techniques using advanced adsorbents for detecting and analyzing a wide range of substances.
-