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2000
Volume 4, Issue 3
  • ISSN: 2452-2716
  • E-ISSN: 2452-2724

Abstract

Self-healing coatings are intended to increase long-term durability and reliability and can be prepared by the use of microcapsules containing a self-healing agent capable of interacting with the matrix and regenerating the system. This review article provides an overview of the state-of-the-art patents published in the field of microcapsule-based self-healing organic coatings since the early 2000s. A discussion regarding coatings for corrosion protection is presented and the different self-healing approaches and mechanisms are also addressed, as well as future challenges and expectations for this kind of coatings.

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/content/journals/caps/10.2174/2452271604666210913103301
2021-12-01
2025-01-10
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References

  1. WeldonD.G. Failure analysis of paints and coatings. Chichester John Wiley & Sons2009
    [Google Scholar]
  2. ZhangH. WangJ. LiuX. WangZ. WangS. High performance self-healing epoxy/polyamide protective coating containing epoxy microcapsules and polyaniline nanofibers for mild carbon steel.Ind. Eng. Chem. Res.20135230101721018010.1021/ie400666a
    [Google Scholar]
  3. VijayanP. AlmaadeedM.A. Containers for self-healing epoxy composites and coating: Trends and advances.Express Polym. Lett.20161050652410.3144/expresspolymlett.2016.48
    [Google Scholar]
  4. AnS. LeeM.W. YarinA. YoonS.S. A review on corrosion-protective extrinsic self-healing: Comparison of microcapsule-based systems and those based on core-shell vascular networks.Chem. Eng. J.201834420622010.1016/j.cej.2018.03.040
    [Google Scholar]
  5. SamadzadehM. BouraS.H. PeikariM. KasirihaS.M. AshrafiA. A review on self-healing coatings based on micro/nanocapsules.Prog. Org. Coat.20106815916410.1016/j.porgcoat.2010.01.006
    [Google Scholar]
  6. ZhangF. JuP. PanM. ZhangD. HuangY. LiG. LiX. Self-healing mechanisms in smart protective coatings: a review.Corros. Sci.2018144748810.1016/j.corsci.2018.08.005
    [Google Scholar]
  7. WhiteS.R. SottosN.R. GeubelleP.H. MooreJ.S. KesslerM.R. SriramS.R. BrownE.N. ViswanathanS. Autonomic healing of polymer composites.Nature2001409682279479710.1038/3505723211236987
    [Google Scholar]
  8. BrownE.N. KesslerM.R. SottosN.R. WhiteS.R. In situ poly (urea- formaldehyde) microencapsulation of dicyclopentadiene.J. Microencapsul.200320671973010.3109/0265204030917808314594661
    [Google Scholar]
  9. JinH. MangunC.L. StradleyD.S. MooreJ.S. SottosN.R. WhiteS.R. Self-healing thermoset using encapsulated epoxy-amine healing chemistry.Polymer (Guildf.)20125358158710.1016/j.polymer.2011.12.005
    [Google Scholar]
  10. LiuX. ZhangH. WangJ. WangZ. WangS. Preparation of epoxy microcapsule based self-healing coatings and their behavior.Surf. Coat. Tech.2012206234976498010.1016/j.surfcoat.2012.05.133
    [Google Scholar]
  11. ChoS.H. AnderssonH.M. WhiteS.R. SottosN.R. BraunP.V. Polydimethylsiloxane-based self-healing materials.Adv. Mater.200618997100010.1002/adma.200501814
    [Google Scholar]
  12. ZhuD.Y. RongM.Z. ZhangM.Q. Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation.Prog. Polym. Sci.201549–5017522010.1016/j.progpolymsci.2015.07.002
    [Google Scholar]
  13. KesslerM.R. WhiteS.R. Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene.J. Polym. Sci. A Polym. Chem.200240142373238310.1002/pola.10317
    [Google Scholar]
  14. LiaoL. ZhangW. XinY. WangH.M. ZhaoY. LiW. Preparation and characterization of microcapsule containing epoxy resin and its self-healing performance of anticorrosion covering material.Chin. Sci. Bull.2011564–543944310.1007/s11434‑010‑4133‑0
    [Google Scholar]
  15. YuanL. GuA. LiangG. Preparation and properties of poly (urea- formaldehyde) microcapsules filled with epoxy resins.Mater. Chem. Phys.20081102–341742510.1016/j.matchemphys.2008.02.035
    [Google Scholar]
  16. SivaT. SathiyanarayananS. Self healing coatings containing dual active agent loaded urea formaldehyde (UF) microcapsules.Prog. Org. Coat.201582576710.1016/j.porgcoat.2015.01.010
    [Google Scholar]
  17. JadhavR.S. HundiwaleD.G. MahulikarP.P. Synthesis and characterization of phenol–formaldehyde microcapsules containing linseed oil and its use in epoxy for self-healing and anticorrosive coating.J. Appl. Polym. Sci.20111192911291610.1002/app.33010
    [Google Scholar]
  18. KumarA. StephensonL.D. MurrayJ.N. Self-healing coatings for steel.Prog. Org. Coat.200655324425310.1016/j.porgcoat.2005.11.010
    [Google Scholar]
  19. KellerM.W. WhiteS.R. SottosN.R. A self-healing poly(dimethyl siloxane) elastomer.Adv. Funct. Mater.2007172399240410.1002/adfm.200700086
    [Google Scholar]
  20. WeihermannW.R.K. MeierM.M. PezzinS.H. Microencapsulated amino-functional polydimethylsiloxane as autonomous external self-healing agent for epoxy systems.J. Appl. Polym. Sci.20191364762710.1002/app.47627
    [Google Scholar]
  21. BlaiszikB.J. SottosN.R. WhiteS.R. Nanocapsules for self-healing materials.Compos. Sci. Technol.2008683–497898610.1016/j.compscitech.2007.07.021
    [Google Scholar]
  22. BraunP ChoS WhiteS SottosN AnderssonH. Self-Healing Polymers.US 20060252852 A12005
  23. BraunPV ChoSH WhiteSR Self-healing coating system.US20070166542A1 / WO2007082153 / EP19739722007
  24. BekasD.G. TsirkaK. BaltzisD. PaipetisA.S. Self-healing materials: A review of advances in materials, evaluation, characterization and monitoring techniques.Compos., Part B Eng.2016879211910.1016/j.compositesb.2015.09.057
    [Google Scholar]
  25. MirabediniS.M. AlizadeganF. Chapter 9, self-healing polymeric coatings containing microcapsules filled with active materials. ThomasS. SurendramA. Self-healing polymer-based systemsElsevier202023525410.1016/B978‑0‑12‑818450‑9.00009‑X
    [Google Scholar]
  26. SilvaA.C.M. RenzettiR.A. AndradaA.S. SinghP. RohatgiP.K. Da SilvaM.C. Adapted synthesis routes and healing evaluation of a self-healing anticorrosive coating.J. Coat. Technol. Res.2020171351136110.1007/s11998‑020‑00356‑x
    [Google Scholar]
  27. UsmanC.A. Chapter: 4. Recent developments in self-healing coatings for corrosion protection. MittalV. Functional nanomaterials and nanotechnologies applications for energy & environmentCentral West Publishing2018
    [Google Scholar]
  28. ThakurV.K. KesslerM.R. Self-healing polymer nanocomposite materials: A review.Polymer (Guildf.)20156936938310.1016/j.polymer.2015.04.086
    [Google Scholar]
  29. PezzinS.H. CoelhoL.A.F. AmicoS.C. PardiniL.C. Thermosets. Structural materials and processes in transportationWeinheimWiley-VCH2013203235
    [Google Scholar]
  30. YuanD. BonabV.S. PatelA. YilmazT. GrossR.A. Manas-ZloczowerI. Design strategy for self-healing epoxy coatings.Coatings2020105010.3390/coatings10010050
    [Google Scholar]
  31. StankiewiczA. SzczygieI. SzczygieB. Self-healing coatings in anti-corrosion applications.J. Mater. Sci.201348238041805110.1007/s10853‑013‑7616‑y
    [Google Scholar]
  32. CottingF. KoebschA. AokiI.V. Epoxy self-healing coating by encapsulated epoxy ester resin in poly (urea-formaldehyde-melamine) microcapsules.Front Mater2019631410.3389/fmats.2019.00314
    [Google Scholar]
  33. BehzadnasabM. MirabediniM. EsfandehM. FarnoodR.R. Evaluation of corrosion performance of a self-healing epoxy-based coating containing linseed oil-filled microcapsules via electrochemical impedance spectroscopy.Prog. Org. Coat.201710521222410.1016/j.porgcoat.2017.01.006
    [Google Scholar]
  34. HuangM. YangJ. Salt spray and EIS studies on HDI microcapsule-based self-healing anticorrosive coatings.Prog. Org. Coat.201477116817510.1016/j.porgcoat.2013.09.002
    [Google Scholar]
  35. SchlemperD.M. PezzinS.H. Self-healing epoxy coatings containing microcapsules filled with different amine compounds - a comparison study.Prog. Org. Coat.202115610625810.1016/j.porgcoat.2021.106258
    [Google Scholar]
  36. KoebschA CottingF AokiIV CoelhoJFP LachtermacherMG Processo de obtenção de revestimento autorregenerante contendo inibidor de corrosão.BR1020130335792017
  37. OdarczenkoMT WhiteSR SottosNR Self-healing coating.US20170158886A12017
  38. Chaloner-GillBM TaylorST Functional self-healing coatings and compositions and methods for forming such coatings.US201700511572017
  39. Sauvant-MoynotV DuvalS GonzalezS ValletJ GrenierJ Self-healing structure and coating used in corrosive environment.EP1591562A22005
  40. StephensonLD ThiesC KumarA SarangapaniS Self-healing coating and microcapsules to make same.US20080152815 A1/US71929932008
  41. KumarA StephensonLD Self-healing coatings using microcapsules to suppress lead dust.US7342057B22008
  42. DubeyR DuttaD ShamiTC RaoKUB Self-healing composition comprising microencapsulated epoxy and hardener inside polyurea microcapsules.IN0613/DEL2010
  43. DongA ZhangP DengL ZhangJ. A kind of double microcapsule compositions of self-repair function and the application on self-repair function protective coating.CN108102456A2018
  44. KumarGA A process for preparing at least one microcapsule to provide self-healing healing properties to corrosion-resistant coating compositions.IN2011KO001142012
  45. KohWG CheongIW ParkSP JangEJ RyuHW HanSW ChoWS ChungUS Microcapsules having self-healing composition and manufacturing method of the microcapsule, and coating material composition and self-healing film having the same.KR101498361 / KR20140133298,2014
  46. MahulikarPP HundiwaleDG JadhavRS Self-healing anticorrosive coating material and process for producing the same.IN2011MU000652011
  47. MaW. Self-healing microcapsules and its preparation method, coating, coating with an epoxy resin composite material.CN1071590702017
  48. ZhaoY WangS MaW SongZ Self-healing microcapsules synthesis method, a self-healing coating with the coating.CN1071381052017
  49. ChungCM YangHI YuHC KimDM Self-healing coating formulation, and self-healing coating material using the same.KR20170045487A/KR101780451B12017
  50. PetersonAM SakulichAR ChenY XiaCT Self-healing coating for reinforcement steel.US20170443792017
  51. XuW KongF ZhangL LiL YangC CaoY ZhangX Self-repairing microcapsule for metal anticorrosive coating and preparation method thereof.CN107312140B2017
  52. MaoQ LyuQ WangR WangY WangZ CuiS LanM Colored self-repairing heat reflecting coating and coating process thereof.CN103881504B>2014
  53. YangJ HuangM Microencapsulation of organic silanes and their use as self healing materials.WO20131378282013
  54. YangJ HuangM Microencapsulation of reactive diisocyanates and the application to self-healing anticorrosion coatings.US2013196071/US89930662013
  55. HenryJJM Nano-based self-healing anti-corrosion coating.WO20121781932012
  56. KwonMJ Self-healing material comprising microcapsule, method for self-healing using the same.KR1020110116293A
  57. MaY ZhangY LiM ZhouH WangX LiB WangJ WangJ Externally-repaired and internally- fixed polyurea-based double-wall self-repairing microcapsule and preparation method thereof.CN107970868B2017
  58. YinZ WangK YangZ FangX Self-repairing coating and their corrosion of a magnetic field in the use of a corrosion-resistant sleeve.CN1072167742018
  59. ScharfS EibenK NieradzikJ RoesslerA JochumW Novel transparent coatings with self-healing properties.DE102012009181A1/EP26621342013
  60. ChilamalaS SinghSK RordriguesPV Multi-layered coating system and its method of preparation.IN2011MU035882014
  61. MoonWH Microcapsule with self-healing.KR201700141372017
  62. SchlemperDM PezzinSH Process of obtaining a self-regenerable coating containing aminated poly(dimethylsiloxane).BR102018009720A22019
  63. WilsonGO KasisomayajulaSV BlanchetteRT Dispersion of microcapsules for self-healing applications.US20150018485A1/WO2015067272015
  64. KeeneyC YollickS ClementsM FaderJ HawkinsJ. Encapsulated anti-corrosion coating.EP11539882001
  65. WhiteS SottosN GeubelleP MooreJ SriramS KesslerM BrownE Multifunctional autonomically healing composite material.US20020111434A12002
  66. WilsonGO CarusoMM BlaiszikBJ HendersonJW BrittC MooreJS WhiteSR SottosNR Systems for self-healing composite materials.US20100331445A12010
  67. WhiteSR MooreJS SottosNR BlaiszikBJ CarusoMM Thermally robust capsule system, and composites including capsules.US20130072596A12013
  68. WhiteSR SottosNR BlaiszikBJ Capsules, methods for making capsules, and self-healing composites including the same.US20080299391A12008
  69. CaiX QuA FuD Epoxy resin nano microcapsule and preparation method thereof.CN104945847B2017
  70. JiangM WangS ZhouM LinA HongZ Preparation method for microcapsules coating air-drying film forming material.CN1041479872014
  71. LentzCM RyanKLM Microcapsules having dual reagents separated by the capsule wall and methods for making same.US20190161626A12020
  72. YeX CaiR RanW JiG ZhangY YuL ZhongJ LaiG GeG DengC ChenJ. Self-repairing anticorrosive coating based on polysilazane microcapsule and preparation method thereof.CN108329794B2018
  73. ZhangY WangZ CuiX DouB LiM XiaoS WangX HeH. A kind of preparation method and product of anti-corrosion self-healing coatings polyaniline microcapsules.CN109796799A2019
  74. PeiY CuiJ Anti-corrosive coating with self-repairing ability, preparation method therefor, and application thereof.WO2019029172A12019
  75. GrunwaldI HoffmannM NoeskeM HollermannG BuchbachSA Composites et matières de revêtement contenant des principes actifs inclus dans des enveloppes en matériau biologique.DE1020110878502013
  76. NoeskeM HollermannG GrunwaldI IhdeJ ScharfS. Composite e.g. fiber composite materials or composite coatings e.g. paint coatings, useful in a component, comprises a matrix material, and microcapsules comprising a shell material consisting of a cell wall and/or a cell membrane.DE1020122161902014
  77. YangZ. Preparation method of self-healing anticorrosive coating.CN102876148B2014
  78. JeongC KimD LeeG ChoE Microcapsule-type self-healing coating solution comprising a silanol-terminated polydimethylsiloxane.KR101951471B12019
  79. WilsonG. Self-healing agent formulations containing liquid corrosion inhibitors.WO2015061522A1/JP6389883B22015
  80. ChenR ChenX TianY LiangB LuoJ LiuT BaiY ChenL TianR JinR WangX YuanP ZhangJ GuoX YuX. A kind of preparation method of the selfreparing water paint based on PU/PUF microcapsules.CN109206971A2019
  81. QianY QiuX LiL YangD LiuW OuyangX LouH YiC Lignosulfonate dispersion self-healing polyurea coating, preparation method therefor, coating layer thereof and application thereof.WO2019134416A12019
  82. WangJ. Composite shell of the microcapsule coating liquid isocyanate production method of a self-reparable.CN1069439692017
  83. YaoL WangH ChenF CongG GaoJ LiW A kind of self-reparing water-base epoxy elastic composite coating material and preparation method thereof.CN107573810B2018
  84. WilsonG. Self-healing polymer material via unsaturated polyesters.WO2014201290A1/JP6566937B22014
  85. XieG PengS ZhangL GuoD LuoJ Preparation method of self-repairing and self-lubricating coating based on micro-texture surface.CN109593442B2019
  86. De JongKL HuN-X BaranyiG Self-healing photoconductive member.EP20989122017
  87. WangW XuL LeeS ChengW XinY. A kind of preparation method of magnetism self-repairing microcapsule.CN105289435B2018
  88. BenkoskiJJ SrinivasanR MaranchiJP Self-healing coatings.US95508552017
  89. LiW ZhaoX Stimulus response-type self-repairing anti-corrosion coating material and preparation method.WO2020221378A12020
  90. ChenQ. A kind of selfreparing anti-corrosion outdoor building graphene coating and preparation method.CN108912870A2018
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  • Article Type:
    Review Article
Keyword(s): anti-corrosion; Coatings; microcapsules; patents; polymer; self-healing
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