Skip to content
2000
Volume 4, Issue 1
  • ISSN: 2665-976X
  • E-ISSN: 2665-9778

Abstract

Introduction

gCN/C

Methods

resulting in the formation of a greater number of reactive sites.

Results

The type-Z heterojunction formed between the CuOQDs and g-CN/C reduced the energy required for electron transition, thereby facilitating the separation of photo-generated electron-hole pairs. The highest photocatalytic degradation efficiency of g-CN/C for tetracycline (TC) was 65.1%, which was 3.3 times that of pure g-CN.

Conclusion

In the photocatalytic process, the main reactive species is O−. The g-CN/C synthesized by stem induction in multi-phase heterojunction form has a stable microstructure to improve the charge separation efficiency. Further, it represents practical photocatalytic environmental protection.

Loading

Article metrics loading...

/content/journals/photocat/10.2174/012665976X334005241021062812
2024-11-01
2026-03-05
Loading full text...

Full text loading...

References

  1. GuoJ. ShenC.H. SunJ. XuX-J. LiX-Y. FeiZ-H. LiuZ-T. WenX-J. Highly efficient activation of peroxymonosulfate by Co3O4/Bi2MoO6 p-n heterostructure composites for the degradation of norfloxacin under visible light irradiation.Separ. Purif. Tech.202125911810910.1016/j.seppur.2020.118109
    [Google Scholar]
  2. ShenC.H. ChenY. XuX.J. LiX.Y. WenX.J. LiuZ.T. XingR. GuoH. FeiZ.H. Efficient photocatalytic H2 evolution and Cr(VI) reduction under visible light using a novel Z-scheme SnIn4S8/CeO2 heterojunction photocatalysts.J. Hazard. Mater.202141612621710.1016/j.jhazmat.2021.126217 34492974
    [Google Scholar]
  3. HasijaV. Singh, P.; Thakur, S.; Nguyen, V.H.; Van Le, Q.; Ahamad, T.; Alshehri, S.M.; Raizada, P.; Matsagar, B.M.; Wu, K.C.W. O and S co-doping induced N-vacancy in graphitic carbon nitride towards photocatalytic peroxymonosulfate activation for sulfamethoxazole degradation.Chemosphere202332013801510.1016/j.chemosphere.2023.138015 36746247
    [Google Scholar]
  4. LiangC. WeiD. ZhangS. RenQ. ShiJ. LiuL. Removal of antibiotic resistance genes from swine wastewater by membrane filtration treatment.Ecotoxicol. Environ. Saf.202121011188510.1016/j.ecoenv.2020.111885 33421714
    [Google Scholar]
  5. WuS. LiX. TianY. LinY. HuY.H. Excellent photocatalytic degradation of tetracycline over black anatase-TiO2 under visible light.Chem. Eng. J.202140612674710.1016/j.cej.2020.126747
    [Google Scholar]
  6. ZhengS. WangY. ChenC. ZhouX. LiuY. YangJ. GengQ. ChenG. DingY. YangF. Current progress in natural degradation and enhanced removal techniques of antibiotics in the environment: A review.Int. J. Environ. Res. Public Health202219171091910.3390/ijerph191710919 36078629
    [Google Scholar]
  7. Kusiak-NejmanE. CzyżewskiA. WanagA. DubickiM. SadłowskiM. WróbelR.J. MorawskiA.W. Photocatalytic oxidation of nitric oxide over AgNPs/TiO2-loaded carbon fiber cloths.J. Environ. Manage.202026211034310.1016/j.jenvman.2020.110343 32250819
    [Google Scholar]
  8. QuJ. ZhangW. BiF. YanS. MiaoX. ZhangB. WangY. GeC. ZhangY. Two-step ball milling-assisted synthesis of N-doped biochar loaded with ferrous sulfide for enhanced adsorptive removal of Cr(VI) and tetracycline from water.Environ. Pollut.202230611939810.1016/j.envpol.2022.119398 35525521
    [Google Scholar]
  9. WangS. SongD. LiaoL. LiM. LiZ. ZhouW. Surface and interface engineering of BiOCl nanomaterials and their photocatalytic applications.Adv. Colloid Interface Sci.202432410308810.1016/j.cis.2024.103088 38244532
    [Google Scholar]
  10. FanD. WangZ. YinM. LiH. HuH. GuoF. FengZ. LiJ. ZhangD. ZhuM. LiZ. Forming of organic/inorganic material heterojunction: Effectively improve the carrier separation rate and solar energy utilization rate.Physica B202467341548610.1016/j.physb.2023.415486
    [Google Scholar]
  11. YaoG. LiuY. LiuJ. XuY. Facile synthesis of porous g-C3N4 with enhanced visible-light photoactivity.Molecules2022276175410.3390/molecules27061754 35335118
    [Google Scholar]
  12. FitoJ. KefeniK.K. NkambuleT.T.I. The potential of biochar-photocatalytic nanocomposites for removal of organic micropollutants from wastewater.Sci. Total Environ.202282915464810.1016/j.scitotenv.2022.154648 35306069
    [Google Scholar]
  13. ZhaoC. RanF. DaiL. LiC. ZhengC. SiC. Cellulose-assisted construction of high surface area Z-scheme C-doped g-C3N4/WO3 for improved tetracycline degradation.Carbohydr. Polym.202125511734310.1016/j.carbpol.2020.117343 33436186
    [Google Scholar]
  14. ZhaoJ. GeS. LiuL. ShaoQ. MaiX. ZhaoC.X. HaoL. WuT. YuZ. GuoZ. Microwave solvothermal fabrication of zirconia hollow microspheres with different morphologies using pollen templates and their dye adsorption removal.Ind. Eng. Chem. Res.201857123124110.1021/acs.iecr.7b04000
    [Google Scholar]
  15. TangF. LiuC. ChenF. QianJ. QiuY. MengX. ChenZ. Preparation of CdS-g-C3N4/C composites via hollyhock stem biotemplate and its photocatalytic property.Ceram. Int.20224819286142862110.1016/j.ceramint.2022.06.175
    [Google Scholar]
  16. LiuC. MaoD. PanJ. QianJ. ZhangW. ChenF. ChenZ. SongY. Fabrication of highly efficient heterostructured Ag-CeO2/g-C3N4 hybrid photocatalyst with enhanced visible-light photocatalytic activity.J. Rare Earths201937121269127810.1016/j.jre.2018.12.018
    [Google Scholar]
  17. JinT. LiuC. ChenF. QianJ. QiuY. MengX. ChenZ. Synthesis of g-C3N4/CQDs composite and its photocatalytic degradation property for Rhodamine B.Carbon Letters20223261451146210.1007/s42823‑022‑00382‑2
    [Google Scholar]
  18. Garg SolankiR. RajaramP. Theoretical analysis of XRD data by X-ray peak profile analysis for estimation of lattice strain and crystallite size and study of the effect of growth temperature in CdS nanoparticles.Mater. Today Proc.202147186384638810.1016/j.matpr.2021.08.172
    [Google Scholar]
  19. WangM. JinC. KangJ. LiuJ. TangY. LiZ. LiS. CuO/g-C3N4 2D/2D heterojunction photocatalysts as efficient peroxymonosulfate activators under visible light for oxytetracycline degradation: Characterization, efficiency and mechanism.Chem. Eng. J.202141612811810.1016/j.cej.2020.128118
    [Google Scholar]
  20. CadanF.M. RibeiroC. AzevedoE.B. Improving g-C3N4:WO3 Z-scheme photocatalytic performance under visible light by multivariate optimization of g-C3N4 synthesis.Appl. Surf. Sci.202153714790410.1016/j.apsusc.2020.147904
    [Google Scholar]
  21. ZhanX. ZhangZ. LinJ. XuJ. WangX. HongB. XiaY. ZengY. Surface atom rearrangement enabling graphitic carbon nitride/sodium alginate gel monolith for ultrafast completely photodegrading ciprofloxacin under visible light.Chem. Eng. J.202448915121810.1016/j.cej.2024.151218
    [Google Scholar]
  22. LiY. ChengC. YangY. DunX.J. GaoJ. JinX-J. A novel electrochemical sensor based on CuO/H-C3N4/rGO nanocomposite for efficient electrochemical sensing nitrite.J. Alloys Compd.20197982576477210.1016/j.jallcom.2019.05.137
    [Google Scholar]
  23. ZhangZ. GongL. ZhanX. HongB. WangX. XiaY. ZengY. Complete photodegradation of tetracycline induced by surface microenvironment of graphitic carbon nitride/silver phosphate.J. Environ. Chem. Eng.202412311258310.1016/j.jece.2024.112583
    [Google Scholar]
  24. AlenaziT.N. AlshariefH.H. AlmahriA. Al-ZahraniH.K. KatuahH.A. ShahR. SaadF.A. El-MetwalyN.M. Optimization on the heterogeneous photocatalytic degradation of Azorubine E122 dye using nanocomposite via CuO nanoparticles with sodium mordenite.J. Mol. Liq.202439612392610.1016/j.molliq.2023.123926
    [Google Scholar]
  25. ZengY. ZhanX. HongB. XiaY. DingY. CaiT. YinK. WangX. YangL. LuoS. Surface atom rearrangement on carbon nitride for enhanced photocatalysis degradation of antibiotics under visible light.Chem. Eng. J.202345213943410.1016/j.cej.2022.139434
    [Google Scholar]
  26. YangJ. LiuZ. WangY. TangX. Construction of a rod-like Bi2O4 modified porous g-C3N4 nanosheets heterojunction photocatalyst for the degradation of tetracycline.New J. Chem.202044239725973510.1039/D0NJ01922D
    [Google Scholar]
  27. HuC. HeJ. LiangJ. LinT. LiuQ. Heterogeneous photo-Fenton catalyst α-Fe2O3@g-C3N4@NH2-MIL-101(Fe) with dual Z-Scheme heterojunction for degradation of tetracycline.Environ. Res.2023231Pt 311631310.1016/j.envres.2023.116313 37270080
    [Google Scholar]
  28. ManikandanV.S. HarishS. ArchanaJ. NavaneethanM. Fabrication of novel hybrid Z-Scheme WO3@g-C3N4@MWCNT nanostructure for photocatalytic degradation of tetracycline and the evaluation of antimicrobial activity.Chemosphere2022287Pt 313205010.1016/j.chemosphere.2021.132050 34583295
    [Google Scholar]
  29. WangZ. WangH. WangZ. HuangD. QinH. HeY. ChenM. ZengG. XuP. Ferrocene modified g-C3N4 as a heterogeneous catalyst for photo-assisted activation of persulfate for the degradation of tetracycline.Colloids Surf. A Physicochem. Eng. Asp.202162612702410.1016/j.colsurfa.2021.127024
    [Google Scholar]
  30. HuangL. LiuH. ZhangT.C. WangY. YuanS. Peroxymonosulfate-Assisted BiVO4/Exfoliated g-C3N4 heterojunction for high-performance photodegradation of tetracycline induced by visible light.Ind. Eng. Chem. Res.20226144164181643010.1021/acs.iecr.2c02458
    [Google Scholar]
  31. WagnerC.D. GaleL.H. RaymondR.H. Two-dimensional chemical state plots: A standardized data set for use in identifying chemical states by x-ray photoelectron spectroscopy.Anal. Chem.197951446648210.1021/ac50040a005
    [Google Scholar]
  32. ZhanX. ZengY. XuJ. XiaY. WangX. TaoF. OuyangJ. LiH. YangL. LuoS. HongB. Tailoring the three-phase microenvironment surface to induce carbon nitride oxide generating ·O2– with 100% selectivity for ultrafast photodegradation tetracycline under visible light.Chem. Eng. J.202346414256410.1016/j.cej.2023.142564
    [Google Scholar]
  33. KarthikP. Naveen KumarT.R. NeppolianB. Redox couple mediated charge carrier separation in g-C3N4/CuO photocatalyst for enhanced photocatalytic H2 production.Int. J. Hydrogen Energy202045137541755110.1016/j.ijhydene.2019.06.045
    [Google Scholar]
  34. ZhangH. ZengY. WangX. ZhanX. XuJ. JinA. HongB. Sea-Urchin carbon nitride with carbon vacancies (C-v) and oxygen substitution (O-s) for photodegradation of Tetracycline: Performance, mechanism insight and pathways.Chem. Eng. J.202244613705310.1016/j.cej.2022.137053
    [Google Scholar]
  35. KadiM.W. MohamedR.M. IsmailA.A. BahnemannD.W. Soft and hard templates assisted synthesis mesoporous CuO/g-C3N4 heterostructures for highly enhanced and accelerated Hg(II) photoreduction under visible light.J. Colloid Interface Sci.202058022323310.1016/j.jcis.2020.07.001 32683119
    [Google Scholar]
  36. LiN. LiuX. ZhouJ. ChenW. LiuM. Encapsulating CuO quantum dots in MIL-125(Ti) coupled with g-C3N4 for efficient photocatalytic CO2 reduction.Chem. Eng. J.202039912578210.1016/j.cej.2020.125782
    [Google Scholar]
  37. ZhanX. ZengY. ZhangH. WangX. JinD. JinH. LuoS. YangL. HongB. The coral-like carbon nitride array: Rational design for efficient photodegradation of tetracycline under visible light.J. Environ. Chem. Eng.202311110920110.1016/j.jece.2022.109201
    [Google Scholar]
/content/journals/photocat/10.2174/012665976X334005241021062812
Loading
/content/journals/photocat/10.2174/012665976X334005241021062812
Loading

Data & Media loading...

This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test