Full text loading...
- ISSN: 1570-1794
- E-ISSN: 1875-6271
-
A Study on the Deoxygenation of Phosphine Oxides by Different Silane Derivatives
- Source: Current Organic Synthesis, Volume 13, Issue 1, Feb 2016, p. 148 - 153
-
- 01 Feb 2016
- Previous Article
- Table of Contents
- Next Article
Abstract
The deoxygenation of phosphine oxides was studied on two model reactions, on the reduction of 3- methyl-1-phenyl-3-phospholene 1-oxide and triphenylphosphine oxide using an aralkylsilane, arylsilanes, diarylsilanes, a disiloxane, a polysiloxane and a disilane under solvent-free, thermal or microwave-assisted conditions. The deoxygenations were optimized, and the reactivity of the silanes was evaluated. User-friendly accomplishments were elaborated.
© Bentham Science Publishers