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image of Epoxidation of Hybrid Oleic Acid Derived From Palm Oil and Waste Cooking Oil For Eco-Friendly Polyol Production

Abstract

Background

Palm oil and waste cooking oil undergo functionalization by introducing epoxy groups onto their double bonds, which are subsequently opened to yield hydroxyl groups.

Objectives

The objective of this paper is to produce epoxidized hybrid oleic acid with an applied heterogeneous catalyst for polyol feedstock.

Methods

peracids are generated during the reaction by mixing an acid (commonly acetic acid or formic acid) with hydrogen peroxide. Range Kutta 4th Order Method of numerical integration was used to develop kinetic modeling for reaction based on the mathematical model.

Results

After 40 minutes of epoxidation reaction, the relative conversion to the oxirane percentage reached its maximum of 51%. Fourier transform infrared spectroscopy detected an absorption peak at 3300 cm-1, suggesting the presence of a hydroxyl group.

Conclusion

Epoxidation of palm oil and waste cooking oil using peracids is an efficient method for converting unsaturated fatty acids into epoxidized oils, which have significant industrial applications.

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2024-09-30
2024-11-19

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/content/journals/rice/10.2174/0124055204338632240925062417
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Epoxidation of Hybrid Oleic Acid Derived From Palm Oil and Waste Cooking Oil For Eco-Friendly Polyol Production
Bentham Science Publishers ; https://doi.org/10.2174/0124055204338632240925062417
/content/journals/rice/10.2174/0124055204338632240925062417
/content/journals/rice/10.2174/0124055204338632240925062417
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  • Article Type:     Research Article
Keywords: kinetic model ; Epoxidation ; waste cooking oil ; palm oil ; biomass conversion

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