The Electrogenerated Cyanomethyl Anion in Organic Synthesis

L. Rossi; M. Feroci; A. Inesi

doi:10.2174/1570193052774135

ISSN: 1570-193X
E-ISSN: 1875-6298

The Electrogenerated Cyanomethyl Anion in Organic Synthesis
Authors: L. Rossi¹, M. Feroci² and A. Inesi³
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¹ Dipartimento di Chimica,Ingegneria Chimica e Materiali; Università degli Studi, Monteluco di Roio, I-67040 L'Aquila, Italy. ² Dipartimento di Chimica,Ingegneria Chimica e Materiali; Università degli Studi, Monteluco di Roio, I-67040 L'Aquila, Italy. ³ Dipartimento di Chimica,Ingegneria Chimica e Materiali; Università degli Studi, Monteluco di Roio, I-67040 L'Aquila, Italy.
Source: Mini-Reviews in Organic Chemistry, Volume 2, Issue 1, Jan 2005, p. 79 - 90
DOI: https://doi.org/10.2174/1570193052774135
- Available online: 01 Jan 2005

Abstract

Suitable electrochemical methodologies for the generation of cyanomethyl anion and some electrochemically induced cyanomethylation reactions of electrophilic substrates are described and discussed. In addition, the electrochemical syntheses of carbamates and chiral oxazolidin-2-ones (under mild conditions and avoiding the use of hazardous chemicals), via a new carboxylating reagent (CH2CN- / CO2), are reported in this article.

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2005-01-01

2025-05-30

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Article Type: Review Article

Keyword(s): carbamates; carboxylating reactions; chiral oxazolidinones; cyanomethyl anion; cyanomethylation reactions; organic electrosyntheses

The Electrogenerated Cyanomethyl Anion in Organic Synthesis

Abstract

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