Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins

Fernando Lopez-Ortiz; Jesus G. Lopez; Ramon Alvarez Manzaneda; Isidro J. Perez Alvarez

doi:10.2174/1570193043488962

ISSN: 1570-193X
E-ISSN:

Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins
Authors: Fernando Lopez-Ortiz¹, Jesus G. Lopez², Ramon Alvarez Manzaneda³ and Isidro J. Perez Alvarez⁴
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Affiliations: ¹ Area de Quimica Organica, Universidad de Almeria, Carretera de Sacramento s / n, 04120 Almeria, Spain. ² Area de Quimica Organica, Universidad de Almeria, Carretera de Sacramento s / n, 04120 Almeria, Spain. ³ Area de Quimica Organica, Universidad de Almeria, Carretera de Sacramento s / n, 04120 Almeria, Spain. ⁴ Area de Quimica Organica, Universidad de Almeria, Carretera de Sacramento s / n, 04120 Almeria, Spain.
Source: Mini-Reviews in Organic Chemistry, Volume 1, Issue 1, Jan 2004, p. 65 - 70
DOI: https://doi.org/10.2174/1570193043488962
- Available online: 01 Jan 2004

Abstract

1,2-Oxaphosphetanes are well established intermediate species in the Wittig reaction. Initially, isolable 1,2-oxaphosphetanes represented a source of structural information aimed at supporting mechanistic studies. The evolution of the subject allows the envisaging of stable 1,2-oxaphosphetanes as precursors for the stereoselective formation of olefins.

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2004-01-01

2024-10-16

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Article Type: Review Article

Keyword(s): olefination; oxaphosphetanes; phosphazenes; phosphorus ylides; spiro-heterocycles; wittig

Isolable 1,2-Oxaphosphetanes: From Curiosities to Starting Materials for the Synthesis of Olefins

Abstract

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