Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates

Paulo Gomes; Corinne Gosmini; Jacques Perichon

doi:10.2174/1570178043488518

ISSN: 1570-1786
E-ISSN: 1875-6255

Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates
Authors: Paulo Gomes¹, Corinne Gosmini² and Jacques Perichon³
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¹ Laboratoire d’Electrochimie, Catalyse et Synthese Organique, UMR 7582, Universite Paris 12 – C.N.R.S, 2, Rue Henri Dunant, F-94320 THIAIS, France. ² Laboratoire d’Electrochimie, Catalyse et Synthese Organique, UMR 7582, Universite Paris 12 – C.N.R.S, 2, Rue Henri Dunant, F-94320 THIAIS, France. ³ Laboratoire d’Electrochimie, Catalyse et Synthese Organique, UMR 7582, Universite Paris 12 – C.N.R.S, 2, Rue Henri Dunant, F-94320 THIAIS, France.
Source: Letters in Organic Chemistry, Volume 1, Issue 2, Apr 2004, p. 105 - 108
DOI: https://doi.org/10.2174/1570178043488518
- Available online: 01 Apr 2004

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Abstract

A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.

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2025-05-31

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Article Type: Review Article

Keyword(s): allylation; cobalt halide; homo-allylic amines; imines

Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates

Abstract

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