Nucleophilic Additions of Niobium Enolates of Oxazolidinones to Aromatic Aldehydes and Aldimines

Carlos Kleber Z. Andrade; Patricia P. Kalil; Rafael O. Rocha; Luana M. Alves; Curt M. A. Panisset

doi:10.2174/1570178043488491

ISSN: 1570-1786
E-ISSN: 1875-6255

Nucleophilic Additions of Niobium Enolates of Oxazolidinones to Aromatic Aldehydes and Aldimines
Authors: Carlos Kleber Z. Andrade¹, Patricia P. Kalil², Rafael O. Rocha³, Luana M. Alves⁴ and Curt M. A. Panisset⁵
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¹ Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil. ² Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil. ³ Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil. ⁴ Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil. ⁵ Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil.
Source: Letters in Organic Chemistry, Volume 1, Issue 2, Apr 2004, p. 109 - 111
DOI: https://doi.org/10.2174/1570178043488491
- Available online: 01 Apr 2004

Abstract

Niobium enolate of oxazolidinone 2 was generated by the combination of NbCl5 and a tertiary amine, which then reacted with benzaldehyde and aldimines. The products were obtained in good yields.

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2004-04-01

2025-06-18

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Article Type: Review Article

Keyword(s): niobium enolate; niobium pentachloride; nucleophilic additions; oxazolidinones

Nucleophilic Additions of Niobium Enolates of Oxazolidinones to Aromatic Aldehydes and Aldimines

Abstract

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