Chiral Linker 1. A Novel Chiral Auxiliary Derived from m-Hydrobenzoin as Enantiomerically Pure Linker for Solid Phase Organic Chemistry

P. Gaertner; C. Schuster; M. Knollmueller

doi:10.2174/1570178043400901

ISSN: 1570-1786
E-ISSN: 1875-6255

Chiral Linker 1. A Novel Chiral Auxiliary Derived from m-Hydrobenzoin as Enantiomerically Pure Linker for Solid Phase Organic Chemistry
Authors: P. Gaertner¹, C. Schuster² and M. Knollmueller³
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¹ Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria ² Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria ³ Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria
Source: Letters in Organic Chemistry, Volume 1, Issue 3, Jul 2004, p. 249 - 253
DOI: https://doi.org/10.2174/1570178043400901
- Available online: 01 Jul 2004

Abstract

The synthesis and utility of a novel, m-hydrobenzoin derived chiral auxiliary in stereoselective α- alkylation reactions using convenient solution chemistry as well as the attachment of an analogous system onto a solid support and its application as a dual chiral auxiliary and linker is described.

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2004-07-01

2025-05-11

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Article Type: Review Article

Keyword(s): alkylation; chiral auxiliary; enolate; hydrobenzoin; linker; polymer support

Chiral Linker 1. A Novel Chiral Auxiliary Derived from m-Hydrobenzoin as Enantiomerically Pure Linker for Solid Phase Organic Chemistry

Abstract

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