Stereocontrol in Organic Synthesis Using Silicon Compounds

Ian Fleming

doi:10.2174/1574089054583731

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Stereocontrol in Organic Synthesis Using Silicon Compounds
By Ian Fleming¹
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Affiliations: ¹ Department of Chemistry, Lensfield Road, Cambridge CB2 1EW, UK.
Source: , Volume 1, Issue 1, Jan 2005, p. 55 - 64
DOI: https://doi.org/10.2174/1574089054583731
- Available online: 01 Jan 2005

Abstract

Electronic control of diastereoselectivity is discussed; only electrophilic attack adjacent to a stereogenic centre carrying an electropositive element 3 makes a coherent story.

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2005-01-01

2025-02-17

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Article Type: Review Article

Keyword(s): anhs rule; crams rule; electropositive elements; molecular orbital theory; nucleophile; paddon-rows calculation; stereoselectivity

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Stereocontrol in Organic Synthesis Using Silicon Compounds

Abstract

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