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2000
Volume 13, Issue 4
  • ISSN: 1570-1794
  • E-ISSN: 1875-6271

Abstract

Ethyl octyl phosphite (EOP), a dialkyl phosphite with mixed alkyl groups was prepared, and utilized in the Kabachnik–Fields reaction. The condensation of EOP, paraformaldehyde and primary or secondary amines used in equimolar quantities afforded new α-aminophosphonates under microwave conditions. Methylation of the -α(alkylamino)phosphonates was also investigated. The double phospha-Mannich reaction of primary amines and two equivalents of EOP and paraformaldehyde furnished new bis(phosphonomethyl)amines.

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/content/journals/cos/10.2174/1570179413666151218202757
2016-08-01
2025-06-21
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