Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes

Joseph M. Fox; Ni Yan

doi:10.2174/1385272053765006

ISSN: 1385-2728
E-ISSN: 1875-5348

Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes
Authors: Joseph M. Fox¹ and Ni Yan²
View Affiliations Hide Affiliations

¹ Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA. ² Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA.
Source: Current Organic Chemistry, Volume 9, Issue 7, May 2005, p. 719 - 732
DOI: https://doi.org/10.2174/1385272053765006
- Available online: 01 May 2005

Abstract

This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.

Article metrics loading...

/content/journals/coc/10.2174/1385272053765006

2005-05-01

2025-05-01

From This Site

/content/journals/coc/10.2174/1385272053765006

dcterms_title,dcterms_subject,pub_keyword

-contentType:Contributor -contentType:Concept -contentType:Institution

10

5

Full text loading...

/content/journals/coc/10.2174/1385272053765006

Article Type: Review Article

Keyword(s): alkylzinc addition; carbometallation; cyclopropene chemistry; cyclopropylbutyrolactones; electrophiles; grignard reagents; hydroboration; natural products synthesis; walsh model

Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes

Abstract

From This Site

Most Read This Month

Most Cited Most Cited RSS feed

Isotope Effects on Chemical Shifts as an Analytical Tool in Structural Studies of Intramolecular Hydrogen Bonded Compounds

Studies of the Solvent Effect Observed in the Absorption Spectra of Certain Types of Schiff Bases

Botrytis Species: An Intriguing Source of Metabolites with a Wide Range of Biological Activities. Structure, Chemistry and Bioactivity of Metabolites Isolated from Botrytis Species.

Diterpenes from Marine Opisthobranch Molluscs

Southern African Hyacinthaceae: Chemistry, Bioactivity and Ethnobotany

Structural Studies of Pyoverdins by Mass Spectrometry

Application of the Deuterium Isotope Effect on NMR Chemical Shift to Study Proton Transfer Equilibrium

Use of Long-Range C-H Heteronuclear Multiple Bond Connectivity in the Assignment of the 13 C NMR Spectra of Complex Organic Molecules

Biologically Active Aliphatic Acetogenins from Specialized Idioblast Oil Cells

Advances in Structural Determination of Saponins and Terpenoid Glycosides