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This study aimed to synthesize a total of seven halogenated amidostilbenes 3a-3f using the Heck cross-coupling method. The synthesized stilbenes underwent further reactions with Lewis acids, such as FeCl3 and SnCl4, resulting in imines 4 and indolines 5, respectively. The structure of all synthesized compounds was elucidated using FTIR, 1D- and 2D-NMR, XRD, and HRMS analysis. Furthermore, the mechanistic details underlying the formation of both imines and indolines were also discussed.
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