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2000
Volume 29, Issue 2
  • ISSN: 1385-2728
  • E-ISSN: 1875-5348

Abstract

For the first time, a sonochemical method has been developed for the structural rearrangement of [5,6]-open mono- and poly adducts of fullerene C containing spirocyclic fragments of camphor analogs into [6,6]-closed isomers. The isomerization reaction occurs with quantitative yield under mild conditions: 1 hour at room temperature. A probable mechanism of sonochemical isomerization has been proposed. Mono- and poly adducts of C fullerene containing spirocyclic fragments of camphor analogues were obtained in the reaction of metal complex catalysis by the Pd(acac)–2PPh–4EtAl system with the participation of fullerene and diazo compounds.

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