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- Volume 7, Issue 3, 2018
Current Catalysis - Volume 7, Issue 3, 2018
Volume 7, Issue 3, 2018
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Graphene-based Nanocatalysts for Oxygen Reduction and Evolution Reactions in Metal-oxygen Batteries
Authors: Brij Kishore, Baljeet Singh and Surender KumarBackground: Graphene and its composites with various transition metals and their oxides are widely studied for their applications in electrochemical energy conversion and storage devices. Graphene, a two-dimensional single atomic layer of the carbon atoms, has a high conductivity and high surface area. For these reasons, it has attracted considerable interest in electrochemical devices, such as batteries and supercapacitors Read More
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Magnetically Recoverable Nano Sulfated Titania Catalysed One Pot Synthesis of 4(3H)-quinazolinone Derivatives
Authors: Sandip S. Sabale and Mariam S. DeganiIntoduction: A highly efficient protocol for the one pot synthesis of 4(3H)-quinazolinones from anthranilic acid, ortho esters and various amines using a magnetically separable solid acid catalyst, nano sulfated TiO2 encapsulated Fe3O4 with microwave irradiation, is described. The plausible reaction mechanism for the synthesis of 4(3H)-quinazolinone, catalyzed by sulfated TiO2 encapsulated magnetic nanomaterial is also de Read More
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Insight into Acetylation of Anisyl Alcohol Using 20% (w/w) Cs2.5H0.5 PW12O40 Supported on Mesocelllular Foam (MCF) Silica
Authors: Kalpesh H. Bhadra and Ganapati D. YadavBackground: Solid acids and superacids based on supported heteropoly acids have become very popular. Use of mesoporous materials such as mesocellular silica foam (MCF) was made in this work for its superior textural properties and stability. Methods: MCF was used as a support for cesium substituted dodecatungstophosphoric acid (DTP). 20% (w/w) Cs2.5H0.5PW12O40 (Cs-DTP)/MCF was used as a superacidic hetero Read More
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Catalytic Activity of Co3O4 Supported on Activated Carbon for Alcohols Oxidation
In this work, the catalytic performance of cobalt oxide supported on activated carbon was studied during the oxidation reaction of several aliphatic/aromatic primary or secondary alcohols. Good results for benzyl alcohol and benzyl alcohol derivatives conversion and selectivity were obtained, while aliphatic, primary, and secondary alcohols in the study exhibited low conversions. The influence of the use of sonication Read More
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Fly Ash Catalyzed Microwave Assisted Multicomponent Synthesis of Trisubstituted Imidazole Derivatives
Authors: Sonali S. Chine, C.S. Patil and Vilas B. GadeBackground: Imidazoles are important class of heterocyclic compounds showing biological activities. Several methods have been investigated till today for the synthesis of triaryl imidazoles. Some of these classical as well as nonclassical methods experiences drawbacks for instance elongated reaction time, expensive catalyst, low yield of product etc. Hence improvement of a competent method is still necessary. This paper rev Read More
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An Efficient, Convenient and One-pot Synthesis of Diversified Benzochromenes Using L-valine as an Organocatalyst: A Green Protocol
Authors: Jyoti Tiwari, Swastika Singh, Deepali Jaiswal, Amit K. Sharma, Shailesh Singh, Jaya Singh and Jagdamba SinghBackground: A versatile, facile, one-pot multi-component protocol for the synthesis of 4Hbenzochromenes using L- valine as organocatalyst in aqueous medium has been developed. Methods: Superior catalytic performance of L- valine, operational simplicity, easy workup procedure and recyclability of the catalyst are the key strengths of reported strategy. Results: Therefore, it is a green alternative to the existing protoco Read More
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Au Nanoparticles Catalyzed Chemoselective Aldehyde Oxidation/Amine Coupling to Imines
More LessBackground: In this work, we aimed to synthesize gold nanoparticles stabilized with Nacetyl- L-cysteine and study their catalytic activity towards the benzaldehyde oxidation as well as the formation of imines. Methods: N-acetyl-L-cysteine stabilized gold nanoparticles were prepared and the catalyst was characterized via spectroscopic techniques such as UV-VIS spectrophotometry and SERS. Gold nanoparticles dimensions we Read More
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Synthesis of 2,3-Dihydroquinazolin-4(1H)-ones Using Carboxylic Acids as Catalyst
Authors: Elham Mir, Ebrahim Mollashahi and Ghasem MarandiIntroduction: A one-pot approach for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones in the reaction between 2-aminobezamide and aromatic aldehydes in the presence of highly available carboxylic acids such as benzilic acid, phthalic acid and salicylic acid has been reported. Material and Methods: Carboxylic acids such as benzilic acid, phthalic acid and salicylic acid, used as efficient catalysts for the synthesis of 2,3-dihydro Read More
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The Effect of Adsorbed Hydroxyl Content on the Surface of TiO2 Nanorod Array and its Photocatalytic Degradation Study
Authors: H.P. Suryawanshi, S.G. Bachhav and D.R. PatilIntroduction: Titanium dioxide (TiO2) nanorod and nanowire structure are an important material in photocatalytic and photoelectrocatalytic application. But, photocatalytic performance of TiO2 nanostructure was limited by electron-hole recombination. The surface adsorbed hydroxyls on TiO2 surface play an important role in photocatalytic and energy applications. It increases the trapping site for electron and hole and pr Read More
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