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Volume 21, Issue 1
  • ISSN: 1573-4110
  • E-ISSN: 1875-6727

Abstract

Aims

By using terephthalic acid, 2, 5-furandicarboxylic acid, and terbium nitrate hexahydrate, a Tb-MOF with a core-shell structure was successfully designed and prepared.

Methods

A one-pot method was employed to design and synthesize core-shell Tb-MOF. The morphology, luminescence performance, and stability were well characterized.

Results

Tb-MOF demonstrated good water stability, acid and alkali resistance, and thermal stability. Tb-MOF was found to have high sensitivity to detect Cr3+, Bi3+, and acetone in an aqueous solution, and the LOD of Cr3+, Bi3+, and acetone were calculated to be 0.18 μM, 4.22 μM, and 0.26%, respectively. The sensing mechanism of Cr3+ and acetone was explained as energy-competitive absorption, and the sensing mechanism of Bi3+ was explained as ion replacement.

Conclusion

The prepared Tb-MOF can be developed as a multifunctional light-emitting sensor with high selectivity.

© 2025 Bentham Science Publishers
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2025-01-01
2024-11-22

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Luminescence Detection of Cr3+, Bi3+, and Acetone in Aqueous Solution by Core-Shell Tb-MOF
Current Analytical Chemistry 21, 57 (2025); https://doi.org/10.2174/0115734110297005240531055254
/content/journals/cac/10.2174/0115734110297005240531055254
/content/journals/cac/10.2174/0115734110297005240531055254
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  • Article Type:     Research Article
Keyword(s): acetone; Bi3+; core-shell; Cr3+; luminescence quenching; metal-organic frameworks; Tb-MOF

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