Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds

Mateo Alajarin; Carmen Lopez-Leonardo; Pilar Llamas-Lorente

doi:10.2174/1570178043488356

ISSN: 1570-1786
E-ISSN: 1875-6255

Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds
Authors: Mateo Alajarin¹, Carmen Lopez-Leonardo² and Pilar Llamas-Lorente³
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¹ Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain. ² Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain. ³ Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain.
Source: Letters in Organic Chemistry, Volume 1, Issue 2, Apr 2004, p. 145 - 147
DOI: https://doi.org/10.2174/1570178043488356
- Available online: 01 Apr 2004

Abstract

Asymmetrically substituted bis(iminophosphoranes) derived from 1,2- bis(diphenylphosphino)ethane are prepared by Michael-type addition of easily available N,P,P-trisubstituted aminophosphanes to P-vinyl iminophosphoranes. Similarly P-alkylations of aminophosphanes with P-vinyl phosphane oxides and sulfides are also disclosed.

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2004-04-01

2025-07-11

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Article Type: Review Article

Keyword(s): aminophosphanes; iminophosphoranes; michael addition; phosphorus

Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds

Abstract

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