Skip to content
2000
Volume 25, Issue 2
  • ISSN: 1385-2728
  • E-ISSN: 1875-5348

Abstract

The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a family of widely used materials. In the catalytic preparation of these materials, palladium(II) catalysts represent the most successful catalytic systems. The production of both alternating and non-alternating polyketones has been achieved, with a great difference in their physical properties. Herein, a variety of palladium(II) catalysts, employed for the copolymerization of CO with various olefinic monomers, such as ethylene, α -olefins, styrene and polar vinyl monomers, are fully summarized. The influence of important factors, such as solvents and counterions on specific copolymerization, is also discussed. This review aims to enlighten the design of new Pd catalysts with improved properties, as well as the development of new polyketone materials.

Loading

Article metrics loading...

/content/journals/coc/10.2174/1385272824999201102221113
2021-01-01
2025-05-09
Loading full text...

Full text loading...

/content/journals/coc/10.2174/1385272824999201102221113
Loading
This is a required field
Please enter a valid email address
Approval was a Success
Invalid data
An Error Occurred
Approval was partially successful, following selected items could not be processed due to error
Please enter a valid_number test