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2000
Volume 15, Issue 2
  • ISSN: 1385-2728
  • E-ISSN: 1875-5348

Abstract

The present review covers the topic of microwave-assisted reduction of organic compounds including catalytic (metalcatalyzed hydrogenation, catalytic transfer hydrogenation) and stochiometric reactions (ionic and transfer hydrogenation). The article is subcategorized with respect to the different functionalities which so far have been subjected to reduction: C-C multiple bonds, carbonyls, N-containing functional groups, aromatics and heteroaromatics, reductive deprotection strategies, and miscellaneous reactions like dehalogenation or hydrogen-deuterium exchange.

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/content/journals/coc/10.2174/138527211793979808
2011-01-01
2025-05-20
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  • Article Type:
    Research Article
Keyword(s): 1H NMR-spectra; [HCOO][NHEt3]; acetophenone; Amberlit; ambient pressure; asymmetric reduction; azetidine; Bechamp-reduction; Burk's catalyst; camphes-terol, sitosterol; Cannizzaro Reaction; carpetimycin; catalytic transfer hydrogenation; CEM Voyager; chalcones; charcoal; chemose-lectivity; chemoselective; chiral diamines; cinnamyl-derivatives; condensations; cyclic io-donium; cycliza-tions; Dehalogenation; deuterated hydride; diformic acid salt; diimine; dioxo-lan; electrophilic substitution; enanti-omeric ratio; Enantioselective hydrogenation; Eschweiler-Clarke methylation; esterification; fatty acids; fine chemistry; formic acid; furanoid sugar-aza-crown ethers; heterogeneous (e.g. Pd/C, Pd/Al2O3); homogeneous and heterogeneous catalysis; homogenous (e.g. Wilkinson catalyst); Huang-Minlon modification; hydrogen acceptor; hydrosilylation; Imatinib; in situ imine-formation; ionic hydrogenation; lactone; Meer-wein-Ponndorf-Verley-reduction (MPV-Reduction); Meerwein-Ponndorf-Verley reaction; metal-catalyzed hydrogenation; microwave chemistry; microwave irradiation; N-butyl-N-methylimidazolium hexafluorophosphate; N-Deprotection; N-PMB (p-methoxybenzoyl); natural product syntheses; ND-functionalization; NH4Cl + Fe as reductant-systems; nucleo-philic; O-Bn-Deprotection; oxidations; p-alkoxylated ben-zonitriles; p-fluoro-m-chloronitrobenzene; p-nitro-o-chlorobenzaldehydoxime; pipecolinic acid; QRS (Quartz-Reactor-System); Raney-Ni; rasp-berry ketone; Reduction Reactions; saturated fatty acids; scavenger; stereoselective synthesis; stochiometric reactions; stoichiometric amounts; Stryker's reagent; synthetic chemistry; tetramethyl-ethylenediamine (TMEDA); TpI2 kinase inhibitors; transfer hydrogenation; triethylamine (NEt3); triethylammonium formate; unsaturated fatty acids; unsaturated moieties (e.g. carbonyl groups); Wolff-Kishner reduction
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