HCOOH/RuCl3·3H2O: An Efficient Hydrogen Transfer System for Highly Chemo- and Stereoselective Semihydrogenation of Diaryl Acetylenes Affording trans-Stilbenes

Jie Li; Renqin Zeng; Ruimao Hua

doi:10.2174/2211544711201020125

ISSN: 2211-5447
E-ISSN:

HCOOH/RuCl3·3H2O: An Efficient Hydrogen Transfer System for Highly Chemo- and Stereoselective Semihydrogenation of Diaryl Acetylenes Affording trans-Stilbenes
By Jie Li, Renqin Zeng and Ruimao Hua
Source: Current Catalysis, Volume 1, Issue 2, Aug 2012, p. 125 - 128
DOI: https://doi.org/10.2174/2211544711201020125
- Available online: 01 Aug 2012

Abstract

RuCl3·3H2O-catalyzed stereoselective transfer semihydrogenation of diarylacetylenes with HCOOH as hydrogen source affording trans-stilbenes in good to high yields is developed.

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2012-08-01

2024-11-26

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Article Type: Research Article

Keyword(s): chemical shifts; chemoselectivity; cis-stilbene; Diarylacetylenes; formic acid; hydrogen transfer; Mass spectra; ruthenium trichloride hydrate; semihydrogenation; stereodivergence; stereoisomers; stereoselectivity; substituents; trans-stilbene

HCOOH/RuCl3·3H2O: An Efficient Hydrogen Transfer System for Highly Chemo- and Stereoselective Semihydrogenation of Diaryl Acetylenes Affording trans-Stilbenes

Abstract

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