Activation of Organic Reactions by Perchlorates

Suvarna S. Deshpande; Anil Kumar

doi:10.2174/1574087054583058

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Activation of Organic Reactions by Perchlorates
Authors: Suvarna S. Deshpande¹ and Anil Kumar²
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Affiliations: ¹ Physical Chemistry Division, National Chemical Laboratory, Pune 411008, India. ² Physical Chemistry Division, National Chemical Laboratory, Pune 411008, India.
Source: , Volume 1, Issue 1, Mar 2005, p. 215 - 232
DOI: https://doi.org/10.2174/1574087054583058
- Available online: 01 Mar 2005

Abstract

Perchlorates have been frequently employed to promote a variety of synthetic transformations under ambient conditions. For example, the LiClO4-diethyl ether solvent medium has proven to be a powerful substitute for external high pressure for Diels-Alder reactions and other organic reactions. In this chapter are discussed several such organic transformations where perchlorates have played highly significant role in promoting their rates and yields.

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2005-03-01

2025-01-14

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Article Type: Review Article

Keyword(s): chiral ligand; cycloaddition reactions; cyclopentadiene; diels-alder reactions; ethyl acrylate; hydrophobic packing; lewis acid catalysts; methylbenzoquinone; nitromethane; trans-piperylene

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Activation of Organic Reactions by Perchlorates

Abstract

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