Solvophobic Activation in Organic Synthesis

Marie C. Scherrmann; Stephanie Norsikian; Andre Lubineau

doi:10.2174/1574087054582950

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Solvophobic Activation in Organic Synthesis
Authors: Marie C. Scherrmann¹, Stephanie Norsikian² and Andre Lubineau³
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Affiliations: ¹ Laboratoire de Chimie Organique Multifonctionnelle (UMR CNRS 8614), Institut de Chimie Moleculaire et des Materiaux d'Orsay, Universite Paris-Sud, 91405 Orsay, France. ² Laboratoire de Chimie Organique Multifonctionnelle (UMR CNRS 8614), Institut de Chimie Moleculaire et des Materiaux d'Orsay, Universite Paris-Sud, 91405 Orsay, France. ³ Laboratoire de Chimie Organique Multifonctionnelle (UMR CNRS 8614), Institut de Chimie Moleculaire et des Materiaux d'Orsay, Universite Paris-Sud, 91405 Orsay, France.
Source: , Volume 1, Issue 1, Mar 2005, p. 341 - 401
DOI: https://doi.org/10.2174/1574087054582950
- Available online: 01 Mar 2005

Abstract

Review of organic reactions in which solvophobic effects could be implied in the activation process is presented with a particular emphasis on reactions performed in water.

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2005-03-01

2024-12-27

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Article Type: Review Article

Keyword(s): entropy; hugues-ingold rules; hydrophobic effects; micelles; non-polar solvents; solvophobicity parameter (sp); standard molar gibbs energy; surfactants; transition-state enthalpy

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Solvophobic Activation in Organic Synthesis

Abstract

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