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2000
Volume 4, Issue 1
  • ISSN: 1874-4648
  • E-ISSN: 1874-4656

Abstract

Nanocomposite optical materials with high refractive index (RI) have been one of the most attractive issues due to their good optical property that can be used in many fields. The method for preparing high RI nanocomposites is to incorporate high RI inorganic nano-building blocks, for example, metal oxides and metal chalcogenide semiconductor nanoparticles into polymer matrices. The general design requirements and synthetic methods of these high RI nanocomposites are discussed in this review. We classify the synthetic methods into two parts: in situ particle generation method and ex situ particle generation method, and all the methods are reviewed. Some optical applications on antireflection coatings, volume holographic recording materials, high RI LED encapsulant materials, photonic band gap materials and other applications are also reviewed. The relevant patents are discussed in this article.

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/content/journals/mats/10.2174/1874464811104010015
2011-01-01
2025-05-20
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  • Article Type:
    Research Article
Keyword(s): -ray irradiation polymerization; 2-carboxyethyl acrylate (CEA); absorption coefficients; Antireflection (AR) Coatings; antireflection coatings; aromatic dianhydrides; Bohr diameters; capping agent; Co-Solvent; compatibility; copolymerization; dip-coating; dispersibility; epoxy resins; ex situ particle generation method; FABRICATION METHODS; Fresnel lenses; high molar refractions; High refractive index; high RI LED encapsulant materials; hologram materials; holographic data storage; holographic exposure; impact resistance; in situ gas/solid reaction; in situ particle generation; In Situ Polymerization; infrared spectrum; interfacial interaction; interference pattern; irreversible agglomeration; light transmittance; light-extraction efficiency; Lorentz-Lorenz equation; mercapto-ethanol (ME); metal chalcogenide; metal oxide; metal oxides; miscibility; N, N-dimethylacrylamide (DMAA); nano-building blocks; nanocomposites; nonlinear optical (NLO) materials; ophthalmic lenses; optical applications; optical dielectric materials; optical filters; optical materials; optical resins; Optical transparency; optical waveguides; optoelectronic; organic-inorganic nanocomposites; Phase separation; phosphoric acid; photochromic; Photonic band gap (PBG) materials; photonic band gap materials; photopolymerizable monomers; photopolymerization; photosensitizer; physisorption; polythiourethane (PTU) oligomers; prisms; quater-nary ammonium cation; Rayleigh's law; reflections hamper device; RI matching method; self-cleaning properties; Snell's law; sol-gel reaction; solar cells, photodetectors; spin-coating; sulfur-containing aromatic diamines; thermal initiation; titanium alkoxides; total internal reflection; Trioctylphos-phine oxide (TOPO); trioctylphosphine (TOP); two-photon lithography; urethanemethacrylate macromer (UMM); UV photoinitiator; UV-curing; volume holographic recording materials; zirconium alkoxides
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