Spectrophotometric Analysis of Edible Salt for Iodate Quantities

Syeda Ayesha

doi:10.2174/0118779468329037240924073632

ISSN: 1877-9468
E-ISSN: 1877-9476

Spectrophotometric Analysis of Edible Salt for Iodate Quantities
By Syeda Ayesha¹
View Affiliations Hide Affiliations

¹ Department of Chemistry, Government First Grade College, Kuvempunagar, Mysore, 570023, India
Source: Current Physical Chemistry, Volume 15, Issue 1, Mar 2025, p. 81 - 87
DOI: https://doi.org/10.2174/0118779468329037240924073632
- Received: 24 Jul 2024
- Accepted: 10 Sep 2024
- Available online: 08 Oct 2024

Abstract

Introduction

The Spectrophotometric method was used to identify iodate by utilizing a class of antidepressants known as imipramine hydrochloride (IPH), desipramine hydrochloride (DPH), clomipramine hydrochloride (CPH), and trimipramine hydrochloride (TPM).

Methods

Iodate in nano amounts can be measured using this method in an acidic medium with 3-methyl-2-benzothiazolinone hydrazone hydrochloride hydrate (MBTH) acting as an electrophilic coupling reagent. The MBTH-IPH/DPH/CPH/TPM method had a blue with a maximum absorbance at 630 nm. Beer, 's law was followed, and the blue color that was produced remained stable for up to 24 hours at room temperature (27°C).

Results

The boundaries depending on the situation for the assessment of the strategy like molar absorptivity and Sandell's sensitivity gave various qualities with various reagents. The method was tested with interference from common 11 cations and 8 anions, and the results obtained were within a reasonable range.

Conclusion

The procedure was used for the determination of iodate in iodized edible salts because iodate is one of the common ions in iodized salt. It was found that the method is reliable and can be used effectively for the determination.

Article metrics loading...

/content/journals/cpc/10.2174/0118779468329037240924073632

2024-10-08

2025-05-30

From This Site

/content/journals/cpc/10.2174/0118779468329037240924073632

dcterms_title,dcterms_subject,pub_keyword

-contentType:Contributor -contentType:Concept -contentType:Institution

10

5

Full text loading...

References

WingerR.J. KönigJ. HouseD.A. Technological issues associated with iodine fortification of foods.Trends Food Sci. Technol.20081929410110.1016/j.tifs.2007.08.002
[Google Scholar]
GilmanA.G. GoodmanL.S. TadT.W. MuradF. The pharmacological basis of therapeutics.New YorkMacmillan Publishers1985
[Google Scholar]
HetzelB.S. An overview of the prevention and control of iodine deficiency disorders; Elsevier: Asterdam, 1987731
[Google Scholar]
AchilliM. RomeleL. Ion chromatographic determination of bromate in drinking water by post-column reaction with fuchsin.J. Chromatogr. A19998471-227127710.1016/S0021‑9673(99)00190‑9 10431364
[Google Scholar]
ArnaudD. SpirosP.A. Ion chromatography in series with conductivity detection and inductively coupled plasma-mass spectrophotometry for the determination of nine halogen, mettaloid and non-mmetal species in drinking water.J. Anal. At. Spectrom.200116575580
[Google Scholar]
BichselY. von GuntenU. Determination of iodide and iodate by ion chromatography with post column reaction and UV/visible detection.Anal. Chem.1999711343810.1021/ac980658j 21662923
[Google Scholar]
HuW. TakeuchiT. HaraguchiH. Electrostatic ion chromatography.Anal. Chem.199365172204220810.1021/ac00065a007
[Google Scholar]
KumarS. MaitiB. MathurP.K. Determination of iodate and sulphate in iodized common salt by ion chromatography with conductivity detection.Talanta200153470170510.1016/S0039‑9140(00)00504‑X 18968158
[Google Scholar]
LiuY. MouS. Determination of bromate and chlorinated haloacetic acids in bottled drinking water with chromatographic methods.Chemosphere20045591253125810.1016/j.chemosphere.2003.12.023 15081766
[Google Scholar]
LiuY. MouS. HeberlingS. Determination of trace level bromate and perchlorate in drinking water by ion chromatography with an evaporative preconcentration technique.J. Chromatogr. A20029561-2859110.1016/S0021‑9673(01)01507‑2 12108672
[Google Scholar]
MohammadA. TiwariS. ChaharJ.P.S. Thin-layer chromatographic separation, identification and determination of certain anions.J. Chromatogr. Sci.199533314314710.1093/chromsci/33.3.143
[Google Scholar]
JakmuneeJ. GrudpanK. Flow injection amperometry for the determination of iodate in iodized table salt.Anal. Chim. Acta20014381-229930410.1016/S0003‑2670(01)00798‑X
[Google Scholar]
TakayanagiK. WongG.T.F. The oxidation of iodide to iodate for the polarographic determination of total iodine in natural waters.Talanta198633545145410.1016/0039‑9140(86)80115‑1 18964121
[Google Scholar]
WongG.T.F. ZhangL.S. Chemical removal of oxygen with sulfite for the polarographic or voltammetric determination of iodate or iodide in seawater.Mar. Chem.1992381-210911610.1016/0304‑4203(92)90070‑Q
[Google Scholar]
YosypchukB. NovotnýL. Determination of iodates using silver solid amalgam electrodes.Electroanalysis20021415-1611381142
[Google Scholar]
ChakrabortyD. DasA.K. Indirect determination of iodate by atomic-absorption spectrophotometry.Talanta198936666967110.1016/0039‑9140(89)80260‑7 18964777
[Google Scholar]
GongB.L. GongG.Q. WangH.C. A fluorescence quenching method for the determination of iodate ion with fluorescein.Fenxi Hauxue199725906908
[Google Scholar]
KamsonO.F. Spectrophotometric determination of iodate, iodide and acids by flow injection analysis.Anal. Chim. Acta198617917947547910.1016/S0003‑2670(00)84495‑5
[Google Scholar]
MendezJ.H. MateosA.A. ParraA.M.J. de-MariaC.G. Iiodometric flow-injection determination of traces of oxidants. Determination of iodate and active chlorine.Quim. Anal.198766067
[Google Scholar]
OgumaK. KitadaK. KurodaR. Microchemical determination of iodate and iodide in sea-waters by flow-injection analysis.Mikrochim. Acta1993110717710.1007/BF01243987
[Google Scholar]
ZhaoX.C. KouZ.X. HuZ. Determination of iodate by flow-injection analysis with 5-Br-PADAP[2-(5-bromo-2-pyridyylazo) -5-diethylamino-o-phenol] and thiocyanate.Mikrochim. Acta19911279283
[Google Scholar]
ZuiO.V. TerletskayaA.V. Rapid chemiluminescence method for the determination of iodate traces.Fresenius J. Anal. Chem.19953512-321221510.1007/BF00321640
[Google Scholar]
AfkhamiA. ZareiA.R. Spectrophotometric determination of periodate and iodate by a differential kinetic method.Talanta200153481582110.1016/S0039‑9140(00)00577‑4 18968171
[Google Scholar]
AfkhamiA. MadrakianT. ZareiA.R. Spectrophotometric determination of periodate, iodate and bromate mixtures based on their reaction with iodide.Anal. Sci.200117101199120210.2116/analsci.17.1199 11990596
[Google Scholar]
EnsafiA.A. DehaghiG.B. Flow injection simultaneous determination of iodate and periodate by spectrophotometric and spectrofloourmetric detection.Anal. Sci.2000161616410.2116/analsci.16.61
[Google Scholar]
ElshahawiM. AlhashemiF. Spectrophotometric determination of periodate or iodate ions by liquid-liquid extraction as an ion-pair using tetramethylammonium iodide.Talanta199643122037204310.1016/S0039‑9140(96)01849‑8 18966695
[Google Scholar]
SyedA.A. SunithaR. Spectrophotometric Methods for the Determination of Iodate inIodized Edible Salt and Periodate in Water Samples.Anal Chem Indian J200761711
[Google Scholar]
WilsonC.O. GisvoldG. DoergeR.F. Wilson and Gisvold’s Textbook of organic medicinal and pharmaceutical chemistry.PhiladelphiaLippincott1982
[Google Scholar]
SyedA.A. KhatoonB.A. SilwadiM.F. New reagents for detection of faecal occult blood.J. Pharm. Biomed. Anal.200124458158610.1016/S0731‑7085(00)00454‑4 11272314
[Google Scholar]
SyedA.A. SilwadiM.F. KhatoonB.A. Imipramine hydrochloride and desipramine hydrochloride as new reagents for detection of microamounts of blood in urine.J. Pharm. Biomed. Anal.2002283-450150710.1016/S0731‑7085(01)00665‑3 12008129
[Google Scholar]
PospíšilováM. PolášekM. SvobodováD. Spectrophotometric study of reactions of substituted phenols with MBTH in alkaline medium: The effect of phenol structure on the formation of analytically useful coloured products.Mikrochim. Acta19981293-420120810.1007/BF01244742
[Google Scholar]